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ChemInform Abstract: Oxidation Reactions of Thiodiglycolic Acid: A Pulse Radiolysis Study.

H. MOHAN, Pervaje N. Moorthy

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Abstract

Abstract Hydrogen abstraction from (I) by HO· is observed whereas the radical cation of (I) is formed in the presence of strong oxidants such as (MeI)·+ 2, Cl·‐ 2, SO·‐ 4 also in CH2Cl2 (UV, kinetics, reduction potential (I)+/(I): 2.0 V vs.

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Abstract Hydrogen abstraction from (I) by HO· is observed whereas the radical cation of (I) is formed in the presence of strong oxidants such as (MeI)·+ 2, Cl·‐ 2, SO·‐ 4 also in CH2Cl2 (UV, kinetics, reduction potential (I)+/(I): 2.0 V vs.

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Available abstract

Abstract Hydrogen abstraction from (I) by HO· is observed whereas the radical cation of (I) is formed in the presence of strong oxidants such as (MeI)·+ 2, Cl·‐ 2, SO·‐ 4 also in CH2Cl2 (UV, kinetics, reduction potential (I)+/(I): 2.0 V vs.

Key concepts: Chemistry, Radiolysis, Hydrogen atom abstraction, Kinetics, Photochemistry, Hydrogen, Redox, Pulse (music)

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