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ChemInform Abstract: Simplified Synthesis and Structural Study of {Ta6Br12} Clusters.

Maxim N. Sokolov⧫, Pavel A. Abramov⧫, М. А. Михайлов, Eugenia V. Peresypkina, A.V. Virovets, Vladimir P. Fedin

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Abstract

Abstract A simple and straightforward method for the preparation of Ta6Br12 cluster compounds is described, The structures of (III) (cubic, space group Fd$\bar 3$m, Z = 8), (IV) (triclinic, P$\bar 1$, Z = 2), (V) (triclinic, P$\bar 1$, Z = 2), and (VI) (orthorhombic, Cmca, Z = 4) are determined by single crystal XRD.

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What this paper is about

Abstract A simple and straightforward method for the preparation of Ta6Br12 cluster compounds is described, The structures of (III) (cubic, space group Fd$\bar 3$m, Z = 8), (IV) (triclinic, P$\bar 1$, Z = 2), (V) (triclinic, P$\bar 1$, Z = 2), and (VI) (orthorhombic, Cmca, Z = 4) are determined by single crystal XRD.

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Available abstract

Abstract A simple and straightforward method for the preparation of Ta6Br12 cluster compounds is described, The structures of (III) (cubic, space group Fd$\bar 3$m, Z = 8), (IV) (triclinic, P$\bar 1$, Z = 2), (V) (triclinic, P$\bar 1$, Z = 2), and (VI) (orthorhombic, Cmca, Z = 4) are determined by single crystal XRD.

Key concepts: Triclinic crystal system, Chemistry, Orthorhombic crystal system, Crystallography, Bar (unit), Cluster (spacecraft), Group (periodic table), Crystal structure

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