Synthesis and electrochemical studies of tetrathiafulvalene derivatives (TTFs) as redox active ligands
Abd El‐Wareth A. O. Sarhan, Makoto Murakami, Taeko Izumi
Abstract
Abd El‐Wareth A. O. Sarhan, Makoto Murakami, Taeko Izumi
Abstract
Abstract A simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF‐DME) is reported. The tetrathifulvalene dimethylester (TTF‐DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of the TTF‐DME was investigated in comparison to the well‐known dibenzotetrathiafulvene (DB‐TTF) by cyclic voltammetry. A two‐electron redox behavior was observed as a two waves.
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Abstract A simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF‐DME) is reported. The tetrathifulvalene dimethylester (TTF‐DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of the TTF‐DME was investigated in comparison to the well‐known dibenzotetrathiafulvene (DB‐TTF) by cyclic voltammetry. A two‐electron redox behavior was observed as a two waves.
Key concepts: Tetrathiafulvalene, Chemistry, Cyclic voltammetry, Redox, Bifunctional, Electrochemistry, Combinatorial chemistry, Inorganic chemistry