2002Journal of Heterocyclic ChemistryRequires access

Synthesis and electrochemical studies of tetrathiafulvalene derivatives (TTFs) as redox active ligands

Abd El‐Wareth A. O. Sarhan, Makoto Murakami, Taeko Izumi

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Abstract

Abstract A simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF‐DME) is reported. The tetrathifulvalene dimethylester (TTF‐DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of the TTF‐DME was investigated in comparison to the well‐known dibenzotetrathiafulvene (DB‐TTF) by cyclic voltammetry. A two‐electron redox behavior was observed as a two waves.

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Abstract A simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF‐DME) is reported. The tetrathifulvalene dimethylester (TTF‐DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of the TTF‐DME was investigated in comparison to the well‐known dibenzotetrathiafulvene (DB‐TTF) by cyclic voltammetry. A two‐electron redox behavior was observed as a two waves.

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Available abstract

Abstract A simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF‐DME) is reported. The tetrathifulvalene dimethylester (TTF‐DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of the TTF‐DME was investigated in comparison to the well‐known dibenzotetrathiafulvene (DB‐TTF) by cyclic voltammetry. A two‐electron redox behavior was observed as a two waves.

Key concepts: Tetrathiafulvalene, Chemistry, Cyclic voltammetry, Redox, Bifunctional, Electrochemistry, Combinatorial chemistry, Inorganic chemistry

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