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ChemInform Abstract: Bicyclo(3.3.1)nonanes as Synthetic Intermediates. Part 17. A Novel Interconversion Between Bicyclo(4.3.1)decane and Tricyclo(4.3.1.0)decane Systems via the Dual Mode of Aldol Cyclization of Bicyclo(4.3.1)decane‐3,8‐dione.

Takefumi Momose, Kasumi Masuda, S. FURUSAWA, Osamu Muraoka, T. ITOOKA

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Abstract

Abstract Ring expansion of the (aminomethyl)hydroxyoxaadamantane (I) is achieved via diazotization and subsequent denitrogenation at 0°C to generate the bicyclic dione (II).

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What this paper is about

Abstract Ring expansion of the (aminomethyl)hydroxyoxaadamantane (I) is achieved via diazotization and subsequent denitrogenation at 0°C to generate the bicyclic dione (II).

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Available abstract

Abstract Ring expansion of the (aminomethyl)hydroxyoxaadamantane (I) is achieved via diazotization and subsequent denitrogenation at 0°C to generate the bicyclic dione (II).

Key concepts: Bicyclic molecule, Decane, Chemistry, Ring (chemistry), Bridged compounds, Stereochemistry, Dual (grammatical number), Medicinal chemistry

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ChemInform Abstract: Bicyclo(3.3.1)nonanes as Synthetic Intermediates. Part 17. A Novel Interconversion Between Bicyclo(4.3.1)decane and Tricyclo(4.3.1.0)decane Systems via the Dual Mode of Aldol Cyclization of Bicyclo(4.3.1)decane‐3,8‐dione. — Research Paper | ScholarLens