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ChemInform Abstract: FLUOROPHOSPHINE COMPLEXES OF RUTHENIUM AND OSMIUM. PART 1. SYNTHESES AND STEREOCHEMISTRY OF DIHYDRIDO‐COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II)

R. A. HEAD, John F. Nixon

Abstract

Abstract Die Umsetzung der Tetrahydrido‐Komplexe (I) mit P‐trifluorid oder P‐difluoriddimethylamid führt abhängig vom stöchiometrischen Verhältnis und den Reaktionsbedingungen zu den cis‐Dihydridomono‐ oder ‐diphosphin‐Komplexen (IIa) und (IIb) bzw. (IIIa) und (IIIb).

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Key concepts: Osmium, Ruthenium, Chemistry, Medicinal chemistry, Organic chemistry, Catalysis