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ChemInform Abstract: Selective Formation of Alkyl Azides Using Trimethylsilyl Azide and Carbonyl Compounds.

Kenichi Nishiyama, Takumi Yamaguchi

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Abstract

Abstract Reaction of the carbonyl compounds (I) with trimethylsilyl azide (II) in the presence of sodium azide and 15‐crown‐5 yields the α‐siloxy azides (III), whereas the analogous reaction catalyzed by tin(II) chloride or zinc chloride produces the gem‐diazides (IV).

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What this paper is about

Abstract Reaction of the carbonyl compounds (I) with trimethylsilyl azide (II) in the presence of sodium azide and 15‐crown‐5 yields the α‐siloxy azides (III), whereas the analogous reaction catalyzed by tin(II) chloride or zinc chloride produces the gem‐diazides (IV).

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Available abstract

Abstract Reaction of the carbonyl compounds (I) with trimethylsilyl azide (II) in the presence of sodium azide and 15‐crown‐5 yields the α‐siloxy azides (III), whereas the analogous reaction catalyzed by tin(II) chloride or zinc chloride produces the gem‐diazides (IV).

Key concepts: Chemistry, Trimethylsilyl azide, Azide, Sodium azide, Alkyl, Trimethylsilyl, Zinc, Organic chemistry

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ChemInform Abstract: Selective Formation of Alkyl Azides Using Trimethylsilyl Azide and Carbonyl Compounds. — Research Paper | ScholarLens