2003•Organic LettersRequires access

Polyfluorination of Aryl Alkyl Sulfides by IF5 with Concomitant Migration of the Arylthio Group

Shinichi Ayuba, Tsuyoshi Fukuhara, Shoji Hara

Abstract

[reaction: see text] In the reaction of p-chlorophenyl alkyl sulfides with IF(5), polyfluorination reaction took place on the alkyl chain with the migration of the arylthio group. Consequently, p-chlorophenyl polyfluoroalkyl sulfides, having 3-7 fluorine atoms depending on alkyl chain length, could be obtained selectively.

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Key concepts: Alkyl, Aryl, Chemistry, Group (periodic table), Concomitant, Medicinal chemistry, Chain (unit), Fluorine