2000Organic LettersRequires access

Rearrangement of Phenylethenes on Reaction with Iodine−Xenon Difluoride

Timothy B. Patrick, Suntian Qian

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Abstract

Phenyl-substituted ethenes react with iodine and xenon difluoride to provide difluorinated products. Iodofluoro intermediates react with xenon difluoride to produce transient iodine difluoride species that lose IF and F(-) and produce carbocations.

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What this paper is about

Phenyl-substituted ethenes react with iodine and xenon difluoride to provide difluorinated products. Iodofluoro intermediates react with xenon difluoride to produce transient iodine difluoride species that lose IF and F(-) and produce carbocations.

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Available abstract

Phenyl-substituted ethenes react with iodine and xenon difluoride to provide difluorinated products. Iodofluoro intermediates react with xenon difluoride to produce transient iodine difluoride species that lose IF and F(-) and produce carbocations.

Key concepts: Xenon difluoride, Chemistry, Difluoride, Iodine, Carbocation, Xenon, Photochemistry, Radiochemistry

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