Rearrangement of Phenylethenes on Reaction with Iodine−Xenon Difluoride
Timothy B. Patrick, Suntian Qian
Abstract
Timothy B. Patrick, Suntian Qian
Abstract
Phenyl-substituted ethenes react with iodine and xenon difluoride to provide difluorinated products. Iodofluoro intermediates react with xenon difluoride to produce transient iodine difluoride species that lose IF and F(-) and produce carbocations.
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Phenyl-substituted ethenes react with iodine and xenon difluoride to provide difluorinated products. Iodofluoro intermediates react with xenon difluoride to produce transient iodine difluoride species that lose IF and F(-) and produce carbocations.
Key concepts: Xenon difluoride, Chemistry, Difluoride, Iodine, Carbocation, Xenon, Photochemistry, Radiochemistry