1998•Synthetic CommunicationsRequires access

Selective and High-Yield Electrosynthesis of (Silyl and Silanylene 1-Methylpyrroles) from 1-Methylpyrrole Bromides

Carole Moreau, Françoise Serein‐Spirau, Michel Bordeau, Claude Biran

Abstract

The sacrificial anode technique proved to be efficient for the selective and competitive silylation of 1-methylpyrrole bromides with trimethylchlorosilane and diorganodichlorosilanes. Linear and cyclic alternated 1-methyl-pyrrolylene-silanylene oligomers were obtained in good to high yields.

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Available abstract

Key concepts: Electrosynthesis, Silylation, Chemistry, Yield (engineering), Anode, Organic chemistry, Medicinal chemistry, Electrochemistry