ChemInform Abstract: Silver‐Mediated anti‐Markovnikov and Markovnikov‐Selective Hydrotrifluoromethylthiolation of Terminal Alkynes.
Wei Wu, Wenpeng Dai, Xinfei Ji, Song Cao
Abstract
Wei Wu, Wenpeng Dai, Xinfei Ji, Song Cao
Abstract
Abstract The direct oxidative hydrotrifluoromethylthiolation of terminal alkynes yields vinyl trifluoromethyl thioethers as anti‐Markovnikov and Markovnikov adducts in moderate to good yields depending on the reaction conditions.
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Abstract The direct oxidative hydrotrifluoromethylthiolation of terminal alkynes yields vinyl trifluoromethyl thioethers as anti‐Markovnikov and Markovnikov adducts in moderate to good yields depending on the reaction conditions.
Key concepts: Markovnikov's rule, Chemistry, Adduct, Combinatorial chemistry, Terminal (telecommunication), Organic chemistry, Regioselectivity, Catalysis