Candice Menozzi, Peter I. Dalko, Janine Cossy
Abstract
[reaction: see text] Ruthenium alkylidene complexes 1-3 mediate hydrosilylation of alkynes with silanes. When triethoxy- or triphenylsilanes are used as silylating agents, the reaction affords alpha-substituted vinylsilanes as major products.
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[reaction: see text] Ruthenium alkylidene complexes 1-3 mediate hydrosilylation of alkynes with silanes. When triethoxy- or triphenylsilanes are used as silylating agents, the reaction affords alpha-substituted vinylsilanes as major products.
Key concepts: Hydrosilylation, Silanes, Chemistry, Ruthenium, Organic chemistry, Polymer chemistry, Catalysis, Silane