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ChemInform Abstract: Chemistry of Organosilicon Compounds. Part 261. Photochemical 1,3‐Silyl Migration in Allylsilanes Occurring with Inversion of Silyl Configuration.

Mitsuo Kira, Takayuki Taki, Hideki Sakurai

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Abstract

Abstract Irradiation of the allylsilanes (I) results in 1,3‐silyl migration and inversion of the configuration at the silicon, producing the isomeric silanes (II), together with the aryldimethylsilanes (III).

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What this paper is about

Abstract Irradiation of the allylsilanes (I) results in 1,3‐silyl migration and inversion of the configuration at the silicon, producing the isomeric silanes (II), together with the aryldimethylsilanes (III).

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Available abstract

Abstract Irradiation of the allylsilanes (I) results in 1,3‐silyl migration and inversion of the configuration at the silicon, producing the isomeric silanes (II), together with the aryldimethylsilanes (III).

Key concepts: Organosilicon, Chemistry, Silylation, Inversion (geology), Photochemistry, Organic chemistry, Catalysis, Geology

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ChemInform Abstract: Chemistry of Organosilicon Compounds. Part 261. Photochemical 1,3‐Silyl Migration in Allylsilanes Occurring with Inversion of Silyl Configuration. — Research Paper | ScholarLens