2019Journal of Thermoplastic Composite MaterialsRequires access

Effect of carbon black loading on mechanical and rheological properties of natural rubber/styrene-butadiene rubber/nitrile butadiene rubber blends

Amir A. Abdelsalam, Sherif Araby, Salwa H. El‐Sabbagh, Ahmed Abdelmoneim, Mohsen A Hassan

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Abstract

This study investigated the effect of carbon black (CB) filler loading on mechanical and rheological properties of natural rubber (NR)/styrene-butadiene rubber (SBR)/nitrile butadiene rubber (NBR) ternary rubber nanocomposites. The nanocomposites were prepared using a melt mixing method. Four different samples with different filler loadings namely S 2 (15 phr), S 3 (30 phr), S 4 (45 phr), and S 5 (60 phr) were prepared in this work. The mechanical properties of these samples were investigated such as tensile strength, stress at 100, 200, and 300% elongations, elongation at break %, tear strength, compression set, compression stress, and crosslink density. Results indicate that minimum torque, maximum torque, tensile strength, stress at 100, 200, and 300% elongations, elongation at break %, tear strength, compression set, compression stress, and crosslink density were increased while the scorch time, cure time, cure rate index, elongation at break %, swelling coefficient, and filler–rubber interaction decrease with increasing CB loading. The higher value of tensile strength for these samples was S 4 (loading with 45-phr CB). Therefore, had higher stiffness compared to the other content ratio. Additionally, S 4 showed 233.58% increment in tensile strength. These results showed that the optimum filler loading can increase the compatibility between CB and NR/SBR/NBR. These results were confirmed by scanning electron microscope micrography.

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What this paper is about

This study investigated the effect of carbon black (CB) filler loading on mechanical and rheological properties of natural rubber (NR)/styrene-butadiene rubber (SBR)/nitrile butadiene rubber (NBR) ternary rubber nanocomposites. The nanocomposites were prepared using a melt mixing method. Four different samples with different filler loadings namely S 2 (15 phr), S 3 (30 phr), S 4 (45 phr), and S 5 (60 phr) were prepared in this work. The mechanical properties of these samples were investigated such as tensile strength, stress at 100, 200, and 300% elongations, elongation at break %, tear strength, compression set, compression stress, and crosslink density. Results indicate that minimum torque, maximum torque, tensile strength, stress at 100, 200, and 300% elongations, elongation at break %, tear strength, compression set, compression stress, and crosslink density were increased while the scorch time, cure time, cure rate index, elongation at break %, swelling coefficient, and filler–rubber interaction decrease with increasing CB loading. The higher value of tensile strength for these samples was S 4 (loading with 45-phr CB). Therefore, had higher stiffness compared to the other content ratio. Additionally, S 4 showed 233.58% increment in tensile strength. These results showed that the optimum filler loading can increase the compatibility between CB and NR/SBR/NBR. These results were confirmed by scanning electron microscope micrography.

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Available abstract

This study investigated the effect of carbon black (CB) filler loading on mechanical and rheological properties of natural rubber (NR)/styrene-butadiene rubber (SBR)/nitrile butadiene rubber (NBR) ternary rubber nanocomposites. The nanocomposites were prepared using a melt mixing method. Four different samples with different filler loadings namely S 2 (15 phr), S 3 (30 phr), S 4 (45 phr), and S 5 (60 phr) were prepared in this work. The mechanical properties of these samples were investigated such as tensile strength, stress at 100, 200, and 300% elongations, elongation at break %, tear strength, compression set, compression stress, and crosslink density. Results indicate that minimum torque, maximum torque, tensile strength, stress at 100, 200, and 300% elongations, elongation at break %, tear strength, compression set, compression stress, and crosslink density were increased while the scorch time, cure time, cure rate index, elongation at break %, swelling coefficient, and filler–rubber interaction decrease with increasing CB loading. The higher value of tensile strength for these samples was S 4 (loading with 45-phr CB). Therefore, had higher stiffness compared to the other content ratio. Additionally, S 4 showed 233.58% increment in tensile strength. These results showed that the optimum filler loading can increase the compatibility between CB and NR/SBR/NBR. These results were confirmed by scanning electron microscope micrography.

Key concepts: Materials science, Natural rubber, Styrene-butadiene, Composite material, Ultimate tensile strength, Compression set, Carbon black, Elongation

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Effect of carbon black loading on mechanical and rheological properties of natural rubber/styrene-butadiene rubber/nitrile butadiene rubber blends — Research Paper | ScholarLens