2018Edelweiss Applied Science and TechnologyOpen access

Thermodynamic Analysis and Calculations of (Fe-Co) Alloy by Modeling and Simulation using Thermo-Calc Software

Syed Mahmood Shah, Nasib Ullah, Bakhtar Ullah, Muhammad Shehzad Khan, Tariq Usman

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Abstract

In this paper Thermodynamic calculation is shown. We have found simulation for phase diagram, Gibbs free energy and Activity curve at different temperatures (1200 K, 1225 K and 1250 K). Phase diagrams, Gibbs free-energy and the component activities of (Fe-Co) alloys system were calculated by Calphad method. Results show that the values of Gibbs energy were negative, which shows the stability of (Fe-Co). Negative deviation had occurred from Raoult’s Law in activities, which indicates that there is strong interaction between Fe and Co in (Fe-Co) alloy. By increasing the temperature the activity increases and deviation in activity decreases. For all the thermodynamic calculations the Thermo-Calc software, databases and Calphad method have used.

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What this paper is about

In this paper Thermodynamic calculation is shown. We have found simulation for phase diagram, Gibbs free energy and Activity curve at different temperatures (1200 K, 1225 K and 1250 K). Phase diagrams, Gibbs free-energy and the component activities of (Fe-Co) alloys system were calculated by Calphad method. Results show that the values of Gibbs energy were negative, which shows the stability of (Fe-Co). Negative deviation had occurred from Raoult’s Law in activities, which indicates that there is strong interaction between Fe and Co in (Fe-Co) alloy. By increasing the temperature the activity increases and deviation in activity decreases. For all the thermodynamic calculations the Thermo-Calc software, databases and Calphad method have used.

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Available abstract

In this paper Thermodynamic calculation is shown. We have found simulation for phase diagram, Gibbs free energy and Activity curve at different temperatures (1200 K, 1225 K and 1250 K). Phase diagrams, Gibbs free-energy and the component activities of (Fe-Co) alloys system were calculated by Calphad method. Results show that the values of Gibbs energy were negative, which shows the stability of (Fe-Co). Negative deviation had occurred from Raoult’s Law in activities, which indicates that there is strong interaction between Fe and Co in (Fe-Co) alloy. By increasing the temperature the activity increases and deviation in activity decreases. For all the thermodynamic calculations the Thermo-Calc software, databases and Calphad method have used.

Key concepts: CALPHAD, Gibbs free energy, Thermodynamics, Phase diagram, Alloy, Component (thermodynamics), Activity coefficient, Materials science

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