2006Proceedings of the Mavlyutov Institute of MechanicsRequires access

Equation of state for liquid water

Robert I. Nigmatulin, Р. Х. Болотнова

Open publisher page 2 citations

Abstract

The equation of state for water (EOSW) in Mi–Gruneisen form with Born–Mayer potential for densities less, than 1 g/cm^3 is developed. The equation is applicable to moderate and high pressures (up to 2·10^12 Pa), in particular, to explosive and static pressures in the range of densities from 0.7 to 3.8 g/cm^3 . The equation for the Gruneisen coefficient that depends not only on the specific volume but also on the temperature is received. The proposed method by the experimental data for dependencies on specific volume and temperature the heat capacity and isochoric temperature coefficient of pressure increase allows to calculate the Gruneisen coefficient and the internal heat energy.

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What this paper is about

The equation of state for water (EOSW) in Mi–Gruneisen form with Born–Mayer potential for densities less, than 1 g/cm^3 is developed. The equation is applicable to moderate and high pressures (up to 2·10^12 Pa), in particular, to explosive and static pressures in the range of densities from 0.7 to 3.8 g/cm^3 . The equation for the Gruneisen coefficient that depends not only on the specific volume but also on the temperature is received. The proposed method by the experimental data for dependencies on specific volume and temperature the heat capacity and isochoric temperature coefficient of pressure increase allows to calculate the Gruneisen coefficient and the internal heat energy.

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Available abstract

The equation of state for water (EOSW) in Mi–Gruneisen form with Born–Mayer potential for densities less, than 1 g/cm^3 is developed. The equation is applicable to moderate and high pressures (up to 2·10^12 Pa), in particular, to explosive and static pressures in the range of densities from 0.7 to 3.8 g/cm^3 . The equation for the Gruneisen coefficient that depends not only on the specific volume but also on the temperature is received. The proposed method by the experimental data for dependencies on specific volume and temperature the heat capacity and isochoric temperature coefficient of pressure increase allows to calculate the Gruneisen coefficient and the internal heat energy.

Key concepts: Isochoric process, Equation of state, Thermodynamics, Grüneisen parameter, Volume (thermodynamics), Explosive material, Internal energy, Heat capacity

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