Preparation and Photocatalytic Properties of NiO/TiO2 Nanotubes by Hydrothermal Method
王竹梅 WANG Zhu-mei, 李月明 LI Yue-ming, Runhua Liao, 沈宗洋 SHEN Zong-yang, 左建林 ZUO Jian-lin
Abstract
王竹梅 WANG Zhu-mei, 李月明 LI Yue-ming, Runhua Liao, 沈宗洋 SHEN Zong-yang, 左建林 ZUO Jian-lin
Abstract
采用水热法,制得了管径约为10~15 nm、管长约为10~300 nm、管壁上附着NiO纳米颗粒的TiO2纳米管复合光催化剂(NiO/TiO2).采用X射线衍射、透射电子显微镜、扫描电镜、X射线光电子能谱及紫外-可见漫反射光谱等技术对催化剂进行了表征;以甲基橙为模拟污染物,评价了纳米管的光催化活性.结果表明:NiO晶粒与TiO2晶粒结合形成p-n异质结,有效地促进了光生电子和空穴的分离;NiO对可见光有强烈的吸收,使复合TiO2纳米管在整个可见光区域均有很好的光吸收;以上两点使NiO/TiO2纳米管可见光下的光催化活性大幅提升,500℃煅烧后纳米管对甲基橙1 h分解比由纯TiO2纳米管的7.0%提升至NiO/TiO2纳米管的95.6%.
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采用水热法,制得了管径约为10~15 nm、管长约为10~300 nm、管壁上附着NiO纳米颗粒的TiO2纳米管复合光催化剂(NiO/TiO2).采用X射线衍射、透射电子显微镜、扫描电镜、X射线光电子能谱及紫外-可见漫反射光谱等技术对催化剂进行了表征;以甲基橙为模拟污染物,评价了纳米管的光催化活性.结果表明:NiO晶粒与TiO2晶粒结合形成p-n异质结,有效地促进了光生电子和空穴的分离;NiO对可见光有强烈的吸收,使复合TiO2纳米管在整个可见光区域均有很好的光吸收;以上两点使NiO/TiO2纳米管可见光下的光催化活性大幅提升,500℃煅烧后纳米管对甲基橙1 h分解比由纯TiO2纳米管的7.0%提升至NiO/TiO2纳米管的95.6%.
Key concepts: Non-blocking I/O, Materials science, Photocatalysis, Hydrothermal circulation, Chemical engineering, Hydrothermal synthesis, Nanotechnology, Chemistry