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ChemInform Abstract: Rearrangements of 5‐ and 6‐Cyano‐2‐norbornyl Cations.

Michael Fermann, Ekkehard Herpers, Wolfgang Kirmse, Regina Neubauer, Franz‐Josef Renneke, Rainer Siegfried, Aribert Wonner, Ursula Zellmer

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Abstract

Abstract Starting from cyclopentadiene and acryl‐/methacrylnitrile, hydroboration of the Diels‐Alder adducts obtained leads to 5‐exo‐ and 6‐exo‐hydroxy‐norbornane‐2‐carbonitriles together with the 5‐ and 6‐oxonitriles.

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What this paper is about

Abstract Starting from cyclopentadiene and acryl‐/methacrylnitrile, hydroboration of the Diels‐Alder adducts obtained leads to 5‐exo‐ and 6‐exo‐hydroxy‐norbornane‐2‐carbonitriles together with the 5‐ and 6‐oxonitriles.

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Method / approach

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Available abstract

Abstract Starting from cyclopentadiene and acryl‐/methacrylnitrile, hydroboration of the Diels‐Alder adducts obtained leads to 5‐exo‐ and 6‐exo‐hydroxy‐norbornane‐2‐carbonitriles together with the 5‐ and 6‐oxonitriles.

Key concepts: 2-Norbornyl cation, Chemistry, Medicinal chemistry

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ChemInform Abstract: Rearrangements of 5‐ and 6‐Cyano‐2‐norbornyl Cations. — Research Paper | ScholarLens