2008•Handbook of Heterogeneous CatalysisRequires access

Spillover Effects

Frank Rößner

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Abstract

Abstract The sections in this article are Introduction Individual Steps of the Hydrogen Spillover Process Adsorption and Activation Primary Spillover Diffusion on the Support Secondary Spillover Phenomena of Hydrogen Spillover A Enhanced Adsorption B Interaction with Support C Spillover‐Assisted Catalytic Phenomena D Reverse Spillover The Nature of Spilling Hydrogen Species A Indications for Ion Pairs B Indications for H 3 Species C Indications for H Atoms D Indication for H + Ions E Theoretical Approach Oxygen Spillover Oxidation Reactions The NEMCA Effect Conclusions

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Abstract The sections in this article are Introduction Individual Steps of the Hydrogen Spillover Process Adsorption and Activation Primary Spillover Diffusion on the Support Secondary Spillover Phenomena of Hydrogen Spillover A Enhanced Adsorption B Interaction with Support C Spillover‐Assisted Catalytic Phenomena D Reverse Spillover The Nature of Spilling Hydrogen Species A Indications for Ion Pairs B Indications for H 3 Species C Indications for H Atoms D Indication for H + Ions E Theoretical Approach Oxygen Spillover Oxidation Reactions The NEMCA Effect Conclusions

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Available abstract

Abstract The sections in this article are Introduction Individual Steps of the Hydrogen Spillover Process Adsorption and Activation Primary Spillover Diffusion on the Support Secondary Spillover Phenomena of Hydrogen Spillover A Enhanced Adsorption B Interaction with Support C Spillover‐Assisted Catalytic Phenomena D Reverse Spillover The Nature of Spilling Hydrogen Species A Indications for Ion Pairs B Indications for H 3 Species C Indications for H Atoms D Indication for H + Ions E Theoretical Approach Oxygen Spillover Oxidation Reactions The NEMCA Effect Conclusions

Key concepts: Spillover effect, Hydrogen spillover, Hydrogen, Ion, Adsorption, Diffusion, Catalysis, Chemistry

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