2002•ECS Proceedings VolumesOpen access

Joint Electrodeposition of Molybdenum, Tungsten and Molybdenum-Tungsten Alloys from Oxy-Halide Melts

Hasbi Kushkhov

Abstract

Melts of KCl-NaCl-NaF-WO 3 , KCl-NaCl-NaF-MoO 3 , and KCl-NaCl-NaF-WO 3 -MoO 3 were investigated by cyclic voltammetry. Multi-electron processes of the joint electroreduction of tungsten and molybdenum oxy-fluoride complexes have been realized in one stage in a narrow interval of potential by adjusting pO of the melt. Molybdenum-tungsten alloys were obtained.

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Key concepts: Molybdenum, Tungsten, Halide, Cyclic voltammetry, Fluoride, Inorganic chemistry, Materials science, Joint (building)