2019•Journal of Chemical & Engineering DataRequires access

Measurement and Correlation of Isobaric Vapor Liquid Equilibrium Data for Cyclopentyl Methyl Ether and Cyclopentanol

Akash Patel, Chintan Modi, Milind Joshipura, Nitin V. Bhate

Abstract

Isobaric vapor–liquid equilibrium data for pure components cyclopentyl methyl ether (CPME) and cyclopentanol (CP) and their binary mixtures was generated using a modified ebulliometer. This data has been reported for five different pressures in the range of 71.50 to 101.79 kPa. Pure component boiling points were correlated using the Antoine equation and compared with the literature data. Binary vapor–liquid equilibrium data was modeled using Wilson, NRTL, and UNIQUAC models. Deviation plots for experimental and predicted temperatures are given. UNIQUAC and NRTL model predictions showed a better fit with the experimental values relative to the Wilson model.

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Key concepts: UNIQUAC, Non-random two-liquid model, Chemistry, Isobaric process, Vapor–liquid equilibrium, Thermodynamics, Ether, Activity coefficient