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Catalytic synthesis of hydrogen peroxide from oxygen and water in the presence of carbon monoxide and phosphine complexes of palladium

Vladimir N. Zudin, Vladimir A. Likholobov, Yu. I. Ermakov

Abstract

Results are presented which show that H/sub 2/O/sub 2/ can be synthesized from O/sub 2/ and H/sub 2/O in the presence of a complex such as (PPh/sub 3/)/sub 2/PdO/sub 2/ with equimolar proportions of H/sub 2/O/sub 2/ and CO/sub 2/ being formed. The reaction proceeds at 20/sup 0/C in a stirred, two-phase water-dichloromethane system. Results of various experiments are tabulated. (BLM)

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Key concepts: Carbon monoxide, Palladium, Catalysis, Phosphine, Chemistry, Hydrogen peroxide, Hydrogen, Oxygen