2018Chemical ScienceOpen access

Simultaneous nitrosylation and N-nitrosation of a Ni-thiolate model complex of Ni-containing SOD

Phan T. Truong, Ellen P. Broering, Stephen P. Dzul, Indranil Chakraborty, Timothy L. Stemmler, Todd C. Harrop

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Abstract

Nitric oxide reacts with a NiSOD model complex to yield a thiolate-ligated/N-nitrosated {NiNO} 10 species with unusually labile Ni–NO bonds.

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Nitric oxide reacts with a NiSOD model complex to yield a thiolate-ligated/N-nitrosated {NiNO} 10 species with unusually labile Ni–NO bonds.

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Available abstract

Nitric oxide reacts with a NiSOD model complex to yield a thiolate-ligated/N-nitrosated {NiNO} 10 species with unusually labile Ni–NO bonds.

Key concepts: Nitrosation, Yield (engineering), Chemistry, S-Nitrosylation, Nitrosylation, Nitric oxide, Medicinal chemistry, Oxide

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