Cerium(IV)‐Promoted Phosphinoylation‐Nitratation of Alkenes
Bin Yang, Shu‐Min Hou, Shi‐Yu Ding, Xiao‐Nan Zhao, Yuan Gao, Xue Wang, Shang‐Dong Yang
Abstract
Bin Yang, Shu‐Min Hou, Shi‐Yu Ding, Xiao‐Nan Zhao, Yuan Gao, Xue Wang, Shang‐Dong Yang
Abstract
Abstract A Cerium(IV)‐promoted phosphinoylation‐nitratation of alkenes is established under mild conditions. In this process, Ceric ammonium nitrate (CAN) acts as a cheap phosphorus‐radical initiator, as well as a nitrate donor. Various β‐nitrooxyphosphonates are delivered in high yield in a one‐pot manner. magnified image
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Abstract A Cerium(IV)‐promoted phosphinoylation‐nitratation of alkenes is established under mild conditions. In this process, Ceric ammonium nitrate (CAN) acts as a cheap phosphorus‐radical initiator, as well as a nitrate donor. Various β‐nitrooxyphosphonates are delivered in high yield in a one‐pot manner. magnified image
Key concepts: Chemistry, Cerium, Ceric ammonium nitrate, Cerium nitrate, Yield (engineering), Nitrate, Ammonium nitrate, Inorganic chemistry