2018Physics and Chemistry of Solid StateOpen access

The Important Thermal Characteristics of Matter and Their Computations with the Use of the Gibbs Potentials

Ya. S. Budzhak, Tadeusz Wacławski

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Abstract

In this paper, the important thermal characteristics of matter (they describe thermodynamic systems in a state of thermodynamic equilibrium) were calculated. There are the following important thermodynamic functions: the system internal energy , the thermal function (or enthalpy) the free Helmholtz energy, the thermo-dynamic potential (or Gibbs free energy), the Gibbs grand thermodynamic potential , the entropy , the specific heat capacity . These functions are explicit functions of system’s parameters, they fulfil some mathe-matical relationships and posses some total differentials. These functions are calculated in this paper and their physical sense is given in the cited works.

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In this paper, the important thermal characteristics of matter (they describe thermodynamic systems in a state of thermodynamic equilibrium) were calculated. There are the following important thermodynamic functions: the system internal energy , the thermal function (or enthalpy) the free Helmholtz energy, the thermo-dynamic potential (or Gibbs free energy), the Gibbs grand thermodynamic potential , the entropy , the specific heat capacity . These functions are explicit functions of system’s parameters, they fulfil some mathe-matical relationships and posses some total differentials. These functions are calculated in this paper and their physical sense is given in the cited works.

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Available abstract

In this paper, the important thermal characteristics of matter (they describe thermodynamic systems in a state of thermodynamic equilibrium) were calculated. There are the following important thermodynamic functions: the system internal energy , the thermal function (or enthalpy) the free Helmholtz energy, the thermo-dynamic potential (or Gibbs free energy), the Gibbs grand thermodynamic potential , the entropy , the specific heat capacity . These functions are explicit functions of system’s parameters, they fulfil some mathe-matical relationships and posses some total differentials. These functions are calculated in this paper and their physical sense is given in the cited works.

Key concepts: Helmholtz free energy, Gibbs free energy, Thermodynamic free energy, Thermodynamic databases for pure substances, Thermodynamic system, Thermodynamic potential, Thermodynamics, Enthalpy

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