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2018•Russian Journal of Applied ChemistryRequires access

Anion-Radical Salts of 7,7,8,8-Tetracyanoquinodimethane (TCNQ) with Cations Based on Amino-Chloropyridines

Tetiana N. Starodub

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Abstract

Anion-radical salts of 7,7,8,8-tetracyanoquinodimethane (TCNQ) with N -methyl-2-amino-5-chloropyridinium and N -methyl-2-chloro-3-aminopyridinium cations of simple and complex compositions were synthesized and studied. The salt (N‒CH 3 ‒2‒Cl 3 NH 2 ‒Py)(TCNQ) is electrically conducting and thermally stable up to 340°C. This enables use of this anion-radical salt in electronics of organic materials.

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Anion-radical salts of 7,7,8,8-tetracyanoquinodimethane (TCNQ) with N -methyl-2-amino-5-chloropyridinium and N -methyl-2-chloro-3-aminopyridinium cations of simple and complex compositions were synthesized and studied. The salt (N‒CH 3 ‒2‒Cl 3 NH 2 ‒Py)(TCNQ) is electrically conducting and thermally stable up to 340°C. This enables use of this anion-radical salt in electronics of organic materials.

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Available abstract

Anion-radical salts of 7,7,8,8-tetracyanoquinodimethane (TCNQ) with N -methyl-2-amino-5-chloropyridinium and N -methyl-2-chloro-3-aminopyridinium cations of simple and complex compositions were synthesized and studied. The salt (N‒CH 3 ‒2‒Cl 3 NH 2 ‒Py)(TCNQ) is electrically conducting and thermally stable up to 340°C. This enables use of this anion-radical salt in electronics of organic materials.

Key concepts: Tetracyanoquinodimethane, Chemistry, Salt (chemistry), Ion, Radical ion, Polymer chemistry, Inorganic chemistry, Medicinal chemistry

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Anion-Radical Salts of 7,7,8,8-Tetracyanoquinodimethane (TCNQ) with Cations Based on Amino-Chloropyridines — Research Paper | ScholarLens