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2018•Chemical ScienceOpen access

Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination

Debabrata Dhara, Pankaj Kalita, Subhadip Mondal, Ramakirushnan Suriya Narayanan, Kaustubh R. Mote, Volker Hüch, Michael A. Zimmer, Cem B. Yildiz, David Scheschkewitz, Vadapalli Chandrasekhar, Anukul Jana

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Abstract

The reversible coordination of an N-heterocyclic carbene (NHC) enhances the reactivity of a diphosphene towards hydrolysis and transfer hydrogenation. The hydrolysis is catalytic in NHC.

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The reversible coordination of an N-heterocyclic carbene (NHC) enhances the reactivity of a diphosphene towards hydrolysis and transfer hydrogenation. The hydrolysis is catalytic in NHC.

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OpenAlex reports 36 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

The reversible coordination of an N-heterocyclic carbene (NHC) enhances the reactivity of a diphosphene towards hydrolysis and transfer hydrogenation. The hydrolysis is catalytic in NHC.

Key concepts: Reactivity (psychology), Carbene, Chemistry, Combinatorial chemistry, Stereochemistry, Organic chemistry, Catalysis, Medicine

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