1989•Journal of High Resolution ChromatographyOpen access

Cyclodextrins as chiral stationary phases in capillary gas chromatography. Part IV: Heptakis(2,3,6‐tri‐O‐pentyl)‐β‐cyclodextrin

Wilfried A. König, Sabine Lutz, Monika Hagen, Ralph Krebber, Gerhard Wenz, Kai.‐U. Baldenius, J. EHLERS, Heindirk tom Dieck

Open full text 56 citations

Abstract

Abstract O‐Perpentylated β‐cyclodextrin has been evaluated as chiral stationary phase in capillary gas chromatography. Enantioselectivity is observed towards many chiral hydroxy compounds, including cyanohydrins and carbohydrates. Most importantly, the enantiomers of many olefins and alkyl halides can be resolved on this chiral phase. The thermal stability of the cyclodextrin derivative exceeds 200°C.

Open-access reader

About this research paper

What this paper is about

Abstract O‐Perpentylated β‐cyclodextrin has been evaluated as chiral stationary phase in capillary gas chromatography. Enantioselectivity is observed towards many chiral hydroxy compounds, including cyanohydrins and carbohydrates. Most importantly, the enantiomers of many olefins and alkyl halides can be resolved on this chiral phase. The thermal stability of the cyclodextrin derivative exceeds 200°C.

Why it matters

OpenAlex reports 56 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Abstract O‐Perpentylated β‐cyclodextrin has been evaluated as chiral stationary phase in capillary gas chromatography. Enantioselectivity is observed towards many chiral hydroxy compounds, including cyanohydrins and carbohydrates. Most importantly, the enantiomers of many olefins and alkyl halides can be resolved on this chiral phase. The thermal stability of the cyclodextrin derivative exceeds 200°C.

Key concepts: Cyclodextrin, Enantiomer, Chemistry, Capillary gas chromatography, Alkyl, Chiral stationary phase, Capillary action, Gas chromatography

Related papers

Back to paper searchBrowse research topicsOriginal source
Cyclodextrins as chiral stationary phases in capillary gas chromatography. Part IV: Heptakis(2,3,6‐tri‐O‐pentyl)‐β‐cyclodextrin — Research Paper | ScholarLens