Brian J. Cook, Chun‐Hsing Chen, Maren Pink, Kenneth George Caulton
Abstract
The behavior of the complex (H 2 L)CoCl 2 , where H 2 L is a bis-(pyrazol-3-yl)pyridine, towards Brønsted bases is studied, to evaluate peripheral NH deprotonation as a route to a dianionic pincer ligand on a d 7 center.
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The behavior of the complex (H 2 L)CoCl 2 , where H 2 L is a bis-(pyrazol-3-yl)pyridine, towards Brønsted bases is studied, to evaluate peripheral NH deprotonation as a route to a dianionic pincer ligand on a d 7 center.
Key concepts: Pincer ligand, Pincer movement, Deprotonation, Dehydrohalogenation, Ligand (biochemistry), Chemistry, Proton, Pyridine