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1.1.4 Synthesis of N-Heterocyclic Carbene Complexes

Mirko Ruamps, G. Lavigne, Vincent César

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Abstract

Abstract This chapter describes the main synthetic pathways to access N-heterocyclic carbene–metal complexes. Routes covered include the complexation of free carbenes, metal-induced decomposition of carbene adducts, in situ generation of carbenes in the presence of metals, transmetalation, and templated synthesis from isocyanides.

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What this paper is about

Abstract This chapter describes the main synthetic pathways to access N-heterocyclic carbene–metal complexes. Routes covered include the complexation of free carbenes, metal-induced decomposition of carbene adducts, in situ generation of carbenes in the presence of metals, transmetalation, and templated synthesis from isocyanides.

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Available abstract

Abstract This chapter describes the main synthetic pathways to access N-heterocyclic carbene–metal complexes. Routes covered include the complexation of free carbenes, metal-induced decomposition of carbene adducts, in situ generation of carbenes in the presence of metals, transmetalation, and templated synthesis from isocyanides.

Key concepts: Carbene, Transmetalation, Adduct, Chemistry, Transition metal carbene complex, Metal, Decomposition, Combinatorial chemistry

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