1986•Journal of Solid State ChemistryRequires access

New phase diagram for the system (1 - x)V/sub 2/O/sub 5/ x xPbO in the domain x < 2/3

P. Grégoire, D. Josso, Pierre Garnier, Gilbert Calvarin

Abstract

Phase diagram of the system (1 - x)V/sub 2/O/sub 5/ x xPbO is revised in the rich V/sub 2/O/sub 5/ region (x < 0.66). Two new eutectic compositions are evidenced: x = 0.4975 (15) (T/sub E1/ = 478/sup 0/C) and x = 0.5035 (15) (T/sub E2/ = 480/sup 0/C). Some melting points are also refined.

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Key concepts: Phase diagram, Eutectic system, X-ray crystallography, Crystallography, Domain (mathematical analysis), Phase (matter), Chemistry, Materials science