2017•CrystEngCommRequires access

Synthesis, structure, and photoluminescent behaviour of molecular lanthanide–2-thiophenecarboxylate–2,2′:6′,2′′-terpyridine materials

Rami J. Batrice, J. August Ridenour, R. Lee Ayscue, Jeffery A. Bertke, Karah E. Knope

Abstract

A lanthanide series incorporating 2-thiophenecarboxylate and terpyridine is presented. Four structure types are observed with differences in the coordination number and nuclearity of the complexes attributed to the effects of the lanthanide contraction.

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Key concepts: Terpyridine, Lanthanide, Lanthanide contraction, Photoluminescence, Chemistry, Materials science, Crystallography, Combinatorial chemistry