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2017•The Journal of Organic ChemistryRequires access

Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Jihan Qurban, Mohamed Elsherbini, Thomas Wirth

Open publisher page 39 citations

Abstract

Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

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What this paper is about

Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

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OpenAlex reports 39 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

Key concepts: Hypervalent molecule, Reagent, Reactivity (psychology), Iodine, Enantiomer, Chemistry, Stereoselectivity, Aryl

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