1999•Acta Physica SinicaOpen access

GROUND STATE, POLARON AND BIPOLARON EXCITATIONS AND THEIR STABILITY IN PPV

Desheng Liu, Zhao Jun-Qing, Jianhua Wei, XIE SHI-JIE, MEI LIANG-MO, 山东大学物理系,济南　250100

Abstract

A tight-binding model for conducting polymer poly(phenylene vinylene) (PPV) has been suggested in the framework of one-dimensional chains. The calculations showed that this model is effective to describe the ground state, polaron and bipolaron excitations in PPV. The stability of polarons and bipolarons was discussed by considering the effect of the dimensions, e-ph and e-e interactions.

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Key concepts: Bipolaron, Polaron, Ground state, Condensed matter physics, Physics, Poly(p-phenylene), Stability (learning theory), State (computer science)