1993•OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)Requires access

Be(3)(AsO4)2. 2H2O, a new berylloarsenate phase containing bridged tetrahedral 3-rings. Technical report, 1 June 1992-31 May 1993

W.T.A. Harrison, Tina M. Nenoff, T. E. GIER, Galen Dean Stucky

Abstract

The high-temperature/high-pressure hydrothermal synthesis and X-ray single crystal structure of Be3(AsO4)2(dot)2H2O is described: the title compound contains a three-dimensional network of BeO4 and AsO4 tetrahedra. The structural motif includes infinite layers of bridged tetrahedral 3- and 4-rings. 9Be MAS NMR data are consistent with the Be-atom environments in the crystal structure.

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Key concepts: Tetrahedron, Crystallography, Hydrothermal circulation, Hydrothermal synthesis, Crystal structure, Atom (system on chip), Phase (matter), Chemistry