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CHEMICAL SEPARATION AND SPECTROGRAPHIC DETERMINATION OF TRACE AMOUNTS OF RARE EARTHS IN SAP MATERIAL. PART II.

E. Cerrai, Z. Hainski, G. Rossi, R. Trucco

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Abstract

A chemical procedure based on reversed phase columnar chromatography and aimed at isolating rare earths from a specimen of solid SAP material is described. The calibration of the spectrographic method is also reported. It has a sensitivity limit of 0.01 mu g per each individual rare earth. The chemical procedure was extensively investigated and checked using radioactive tracers. By using a 5-g sample a solution of pure rare earths was obtained in a chloride medium. The sensitivity limit of the spectrographic method is low enough to permit the use of a sample of reduced weight (e.g. 1 g). (auth)

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A chemical procedure based on reversed phase columnar chromatography and aimed at isolating rare earths from a specimen of solid SAP material is described. The calibration of the spectrographic method is also reported. It has a sensitivity limit of 0.01 mu g per each individual rare earth. The chemical procedure was extensively investigated and checked using radioactive tracers. By using a 5-g sample a solution of pure rare earths was obtained in a chloride medium. The sensitivity limit of the spectrographic method is low enough to permit the use of a sample of reduced weight (e.g. 1 g). (auth)

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Available abstract

A chemical procedure based on reversed phase columnar chromatography and aimed at isolating rare earths from a specimen of solid SAP material is described. The calibration of the spectrographic method is also reported. It has a sensitivity limit of 0.01 mu g per each individual rare earth. The chemical procedure was extensively investigated and checked using radioactive tracers. By using a 5-g sample a solution of pure rare earths was obtained in a chloride medium. The sensitivity limit of the spectrographic method is low enough to permit the use of a sample of reduced weight (e.g. 1 g). (auth)

Key concepts: Rare earth, Detection limit, Trace Amounts, Chemistry, Calibration, Analytical Chemistry (journal), Radiochemistry, Mineralogy

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