Nadir ozone profile retrieval from SCIAMACHY and its application to the Antarctic ozone hole in the period 2003–2011

Abstract. The depletion of the Antarctic ozone layer and its changing vertical distribution has been monitored closely by satellites in the past decades ever since the Antarctic ozone hole was discovered in the 1980's. Ozone profile retrieval from nadir-viewing satellites operating in the ultraviolet-visible range requires accurate calibration of level-1 (L1) radiance data. Here we study the effects of calibration on the derived level-2 (L2) ozone profiles and apply the retrieval to the Antarctic ozone hole region. We retrieve nadir ozone profiles from the SCIAMACHY instrument that flew on-board Envisat using the Ozone ProfilE Retrieval Algorithm) (OPERA) developed at KNMI with a focus on the stratospheric ozone. We study and assess the quality of these profiles and compare retrieved (L2) products from L1 SCIAMACHY versions 7 and 8 indicated as respectively (v7, v8) data from the years 2003–2011 without further radiometric correction. From validation of the profiles against ozone sonde measurements, we find that the v8 performs better due to correction for the scan-angle dependency of the instrument's optical degradation. The instrument spectral response function can still be improved for the L1 v8 data with a shift and squeeze. We find that the contribution from this improvement is a few percent residue reduction compared to a reference in the solar irradiance spectra. Validation for the years 2003 and 2009 with ozone sondes shows deviations of SCIAMACHY ozone profiles of 0.8 %–15 % in the stratosphere and 2.5 %–100 % in the troposphere, depending on the latitude and the L1 version used. Using L1 v8 for the years 2003–2011 leads to deviations of ~ 1 %–11 % in stratospheric ozone and ~ 1 %–45 % in tropospheric ozone. Application of SCIAMACHY v8 data on the Antarctic ozone hole shows that most ozone is depleted in the latitude range from 70° S to 90° S. The minimum integrated ozone column consistently occurs around 15 September for the years 2003–2011. Furthermore from the ozone profiles for all these years we observe that the value of ozone column per layer reduces to almost zero at a pressure of 100 hPa in the latitude range of 70° S to 90° S, as was found from other observations.