Determination of stability constants of some actinide complexes. II. Nitrate and chloride complexes of uranium, neptunium, plutonium and americium
H. Lahr, H. Lahr, Sponsor not identified, W. Knoch
Abstract
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H. Lahr, H. Lahr, Sponsor not identified, W. Knoch
Abstract
Open-access reader
Stability constants of the nitrato complexes of several aclinidca j have liwn determined urn^r identical experimental con-; ditions: t'-lV.U-VI; Xp-lV, Xp-V.Xp-VI; Pu-jll, JViV, j Pu-\T; Am-III.The ionic strength was held conntant {« u H) J-' by addition of HCJ0 4 .A collection of known constants is ' yivcu for comparison.A system a lie relation between cationio J radius, ionic charge and complex strength within u aeries of } actinides of equal vaUnrv or liiH'crent oxidation states of one : element could not be established.
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Stability constants of the nitrato complexes of several aclinidca j have liwn determined urn^r identical experimental con-; ditions: t'-lV.U-VI; Xp-lV, Xp-V.Xp-VI; Pu-jll, JViV, j Pu-\T; Am-III.The ionic strength was held conntant {« u H) J-' by addition of HCJ0 4 .A collection of known constants is ' yivcu for comparison.A system a lie relation between cationio J radius, ionic charge and complex strength within u aeries of } actinides of equal vaUnrv or liiH'crent oxidation states of one : element could not be established.
Key concepts: Neptunium, Americium, Plutonium, Actinide, Uranium, Chemistry, Analytical Chemistry (journal), Radiochemistry