1970Unpublished venueOpen access

Determination of stability constants of some actinide complexes. II. Nitrate and chloride complexes of uranium, neptunium, plutonium and americium

H. Lahr, H. Lahr, Sponsor not identified, W. Knoch

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Abstract

Stability constants of the nitrato complexes of several aclinidca j have liwn determined urn^r identical experimental con-; ditions: t'-lV.U-VI; Xp-lV, Xp-V.Xp-VI; Pu-jll, JViV, j Pu-\T; Am-III.The ionic strength was held conntant {« u H) J-' by addition of HCJ0 4 .A collection of known constants is ' yivcu for comparison.A system a lie relation between cationio J radius, ionic charge and complex strength within u aeries of } actinides of equal vaUnrv or liiH'crent oxidation states of one : element could not be established.

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Stability constants of the nitrato complexes of several aclinidca j have liwn determined urn^r identical experimental con-; ditions: t'-lV.U-VI; Xp-lV, Xp-V.Xp-VI; Pu-jll, JViV, j Pu-\T; Am-III.The ionic strength was held conntant {« u H) J-' by addition of HCJ0 4 .A collection of known constants is ' yivcu for comparison.A system a lie relation between cationio J radius, ionic charge and complex strength within u aeries of } actinides of equal vaUnrv or liiH'crent oxidation states of one : element could not be established.

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Available abstract

Stability constants of the nitrato complexes of several aclinidca j have liwn determined urn^r identical experimental con-; ditions: t'-lV.U-VI; Xp-lV, Xp-V.Xp-VI; Pu-jll, JViV, j Pu-\T; Am-III.The ionic strength was held conntant {« u H) J-' by addition of HCJ0 4 .A collection of known constants is ' yivcu for comparison.A system a lie relation between cationio J radius, ionic charge and complex strength within u aeries of } actinides of equal vaUnrv or liiH'crent oxidation states of one : element could not be established.

Key concepts: Neptunium, Americium, Plutonium, Actinide, Uranium, Chemistry, Analytical Chemistry (journal), Radiochemistry

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Determination of stability constants of some actinide complexes. II. Nitrate and chloride complexes of uranium, neptunium, plutonium and americium — Research Paper | ScholarLens