Influence of Amphiphiles on Percolation of AOT-Based Microemulsions Prediction Using Artificial Neural Networks
Gonzalo Astray, A. Cid, O. Moldes, Juan Carlos Mejuto
Abstract
Open-access reader
Gonzalo Astray, A. Cid, O. Moldes, Juan Carlos Mejuto
Abstract
Open-access reader
In this chapter, the ability of artificial neural networks was evaluated to predict the influence of amphiphiles as additive upon the electrical percolation of dioctyl sodium sulfosuccinate (AOT)/isooctane/water microemulsions. In particular, water/AOT/isooctane microemulsion behaviour has been modelled. These microemulsions have been developed in presence of 1-n-alcohols, 2-n-alcohols, n-alkylamines and n-alkyl acids. In all cases, a neural network has been obtained to predict with accuracy the experimental behaviour to identify the physico-chemical variables (such as additive concentration, molecular mass, log P, pKa or chain length) that exert a greater influence on the model. All models are valuable tools to evaluate the percolation temperature for AOT-based microemulsions.
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In this chapter, the ability of artificial neural networks was evaluated to predict the influence of amphiphiles as additive upon the electrical percolation of dioctyl sodium sulfosuccinate (AOT)/isooctane/water microemulsions. In particular, water/AOT/isooctane microemulsion behaviour has been modelled. These microemulsions have been developed in presence of 1-n-alcohols, 2-n-alcohols, n-alkylamines and n-alkyl acids. In all cases, a neural network has been obtained to predict with accuracy the experimental behaviour to identify the physico-chemical variables (such as additive concentration, molecular mass, log P, pKa or chain length) that exert a greater influence on the model. All models are valuable tools to evaluate the percolation temperature for AOT-based microemulsions.
Key concepts: Microemulsion, Percolation (cognitive psychology), Artificial neural network, Amphiphile, Alkyl, Materials science, Chemistry, Chemical engineering