2012•Unpublished venueRequires access
Control of molecular weight using RITP-soap free emulsion polymerization
김여주
Open publisher page 0 citations
Abstract
Chapter 1. INTRODUCTION 1
Chapter 2. THEORITICAL BACKGROUND 3
2.1 Control of Free-Radical Polymerization by Chain Transfer Methods 3
2.1.1 Traditional Methods of Chain Transfer 3
2.2.1.1 Thiols as chain transfer agents 4
2.1.1.2 Halomethanes as chain transfer agents 6
2.1.1.3 Disulfides as Chain Transfer Agents 7
2.1.1.4 Other reagents as Chain Transfer Agents 9
2.1.2 The catalytic Chain transfer Process 10
2.1.3 The Addition-Fragmentation Chain Transfer Process 11
2.1.4 The Reversible Addition-Fragmentation Chain Transfer Process 13
2.1.4.1 Thiocarbonylthio Compounds as RAFT Agent 15
2.1.4.2 Mechanism of RAFT Polymerization with Thiocarbonylthio Compounds 16
2.1.4.3 RAFT Polymerization 17
2.1.4.3.1 Chain transfer Constants 18
2.1.4.3.2 Degree of Livingness 22
2.2 Reverse Iodine Transfer Polymerization 23
2.2.1 Introduction on Reverse Iodine Transfer Polymerization (RITP) 23
2.2.2 Study of the RITP Mechanism 26
2.2.3 Study of the Inhibition