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Ir-Catalyzed Allylic Amination and Etherification

C. Welter, A. Dahnz, B. Brunner, S. Streiff, P. Dübon, G. Helmchen

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Abstract

Significance This system allows for highly ste­reoselective intramolecular allylic aminations and etherifications as well as intermolecular allylic amination followed by intramolecular cyclization (shown). Low catalyst loading (2 mol%), and fast reaction times make this a suitable system for the synthesis of various ring sized N-heterocycles.

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Significance This system allows for highly ste­reoselective intramolecular allylic aminations and etherifications as well as intermolecular allylic amination followed by intramolecular cyclization (shown). Low catalyst loading (2 mol%), and fast reaction times make this a suitable system for the synthesis of various ring sized N-heterocycles.

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Available abstract

Significance This system allows for highly ste­reoselective intramolecular allylic aminations and etherifications as well as intermolecular allylic amination followed by intramolecular cyclization (shown). Low catalyst loading (2 mol%), and fast reaction times make this a suitable system for the synthesis of various ring sized N-heterocycles.

Key concepts: Amination, Allylic rearrangement, Chemistry, Intramolecular force, Intermolecular force, Catalysis, Ring (chemistry), Combinatorial chemistry

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