Chemical constituents of Cycas riuminiana
Vincent Antonio S. Ng, Esperanza Maribel G. Agoo, Chien‐Chang Shen, Consolacion Y. Ragasa
Abstract
Vincent Antonio S. Ng, Esperanza Maribel G. Agoo, Chien‐Chang Shen, Consolacion Y. Ragasa
Abstract
Chemical investigation of the dichlroromethane extr acts of Cycas riuminiana, a plant native to the Phi lippines, afforded α -tocopherol ( 1 ), phytyl fatty acid ester ( 2 ),squalene( 3 ),lutein ( 4 ), chlorophyll a ( 5 ), long chain 1-alkene, and linoleic acid from the leaflets; a mixture of β -sitosterol ( 6 ) and stigmasterol ( 7 ) from the petiole and rachis, and roots; 6 andtriacylglycerol ( 8 ) from thesarcotesta; and 6 , 8 , anda mixture of methyl fatty acid ester ( 9 ) and β - sitosteryl fatty acid ester ( 10 )from the endotesta. The structure of 1 was elucidated by extensive 1D and 2D NMR spectroscopy, while those of 2 - 10 were identified by comparison of their NMR data wit h literature data.
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Chemical investigation of the dichlroromethane extr acts of Cycas riuminiana, a plant native to the Phi lippines, afforded α -tocopherol ( 1 ), phytyl fatty acid ester ( 2 ),squalene( 3 ),lutein ( 4 ), chlorophyll a ( 5 ), long chain 1-alkene, and linoleic acid from the leaflets; a mixture of β -sitosterol ( 6 ) and stigmasterol ( 7 ) from the petiole and rachis, and roots; 6 andtriacylglycerol ( 8 ) from thesarcotesta; and 6 , 8 , anda mixture of methyl fatty acid ester ( 9 ) and β - sitosteryl fatty acid ester ( 10 )from the endotesta. The structure of 1 was elucidated by extensive 1D and 2D NMR spectroscopy, while those of 2 - 10 were identified by comparison of their NMR data wit h literature data.
Key concepts: Stigmasterol, Chemistry, Linoleic acid, Fatty acid, Lutein, Squalene, Nuclear magnetic resonance spectroscopy, Alkene