2017•Inorganic ChemistryRequires access

Synthesis of Mono-, Di-, and Trinuclear Rhodium Diphosphine Complexes Containing Light-Harvesting Fluorene Backbones

Yuko Matsusaka, Shoji Shitaya, Kotohiro Nomura, Akiko Inagaki

Abstract

Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit. The presence of Rh-Rh bonding interactions is suggested by density functional theory studies.

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Key concepts: Rhodium, Chemistry, Diphosphines, Fluorene, Density functional theory, Catalysis, Organic chemistry, Polymer