2016•Journal of Analytical & Pharmaceutical ResearchRequires access

On Two Kinds of Equilibrium Constants in an Extraction System: Does an Interfacial Equilibrium Potential Control the Equilibrium Constant?

Yoshihiro Kudo

Abstract

Two kinds of equilibrium constants were discussedbased on a thermodynamic cycle of overall extraction equilibrium Consequently it was clarified that the individual distribution constants of cation and anion into an organic o phase is controlled by an equilibrium potential at the water o solution interface

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Key concepts: Equilibrium constant, Partition equilibrium, Constant (computer programming), Thermodynamics, Equilibrium thermodynamics, Phase equilibrium, Thermodynamic equilibrium, Solubility equilibrium