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Effect of STAC on Structure of Biotite when Biotite Transform to Hydrated Ba-Mica

Wei Yu, Zhi liang Huang, Xiao Yu Huang

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Abstract

After Ba2+/K+ ion exchange, hydrated Ba2+ replaced K+ from interlayer spacing of biotite. original biotite transformed to vermiculite-type hydrated Ba-mica. in order to study the effect of long-chain alkylammonium on biotite after structure changes, biotite, hydrated Ba-mica and mixing mica (A mixture of biotite and hydrated Ba-mica) were used to be modified by STAC (octadecyl trimethylammonium chloride). Fourier transform infrared spectroscopy and powder X-ray diffraction spectroscopywere were used to characterize the obtained samples to reveal the changes of interlayer spacing and basal spacing. The results showed that STA+ could not enter into the interlayer spacing of biotite but enter into that of hydrated Ba-mica and mixing mica. Almost all basal spacing of Ba-mica and mixing mica were increased to 2.8nm.

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What this paper is about

After Ba2+/K+ ion exchange, hydrated Ba2+ replaced K+ from interlayer spacing of biotite. original biotite transformed to vermiculite-type hydrated Ba-mica. in order to study the effect of long-chain alkylammonium on biotite after structure changes, biotite, hydrated Ba-mica and mixing mica (A mixture of biotite and hydrated Ba-mica) were used to be modified by STAC (octadecyl trimethylammonium chloride). Fourier transform infrared spectroscopy and powder X-ray diffraction spectroscopywere were used to characterize the obtained samples to reveal the changes of interlayer spacing and basal spacing. The results showed that STA+ could not enter into the interlayer spacing of biotite but enter into that of hydrated Ba-mica and mixing mica. Almost all basal spacing of Ba-mica and mixing mica were increased to 2.8nm.

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Available abstract

After Ba2+/K+ ion exchange, hydrated Ba2+ replaced K+ from interlayer spacing of biotite. original biotite transformed to vermiculite-type hydrated Ba-mica. in order to study the effect of long-chain alkylammonium on biotite after structure changes, biotite, hydrated Ba-mica and mixing mica (A mixture of biotite and hydrated Ba-mica) were used to be modified by STAC (octadecyl trimethylammonium chloride). Fourier transform infrared spectroscopy and powder X-ray diffraction spectroscopywere were used to characterize the obtained samples to reveal the changes of interlayer spacing and basal spacing. The results showed that STA+ could not enter into the interlayer spacing of biotite but enter into that of hydrated Ba-mica and mixing mica. Almost all basal spacing of Ba-mica and mixing mica were increased to 2.8nm.

Key concepts: Mica, Biotite, Fourier transform infrared spectroscopy, Vermiculite, Infrared spectroscopy, Mineralogy, Muscovite, Materials science

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Effect of STAC on Structure of Biotite when Biotite Transform to Hydrated Ba-Mica — Research Paper | ScholarLens