2016•Unpublished venueRequires access
Statistical Thermodynamics Basis of Equations of State
Juan H. Vera, Grażyna Wilczek-Vera
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Abstract
The starting point for the statistical thermodynamics justification of equations of state for pure compounds is Equation 24.13 , namely, 24.13 P = − ( ∂ A ∂ V ) T , n = k T ( ∂ ln Q ∂ V ) T , n https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781315399065/4741cd52-f3e4-43ff-9242-14456c3d0226/content/equ24_13a.tif"/> with 24.5 Q ≡ ∑ j e − E j k T https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781315399065/4741cd52-f3e4-43ff-9242-14456c3d0226/content/equ24_05a.tif"/>