2003Zenodo (CERN European Organization for Nuclear Research)Open access

Analytical application of p-sulfonamidophenylazo-bis-acetoxime in the spectrophotometric determination of iron(III)

Saba Khan, Rekha Dashora, Anita Mehta, A.K. Goswami

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Abstract

Department of Chemistry, M. L. Sukhadia University, Udaipur-313 00 I, India E-mail : akumargoswami@rediffmail.com Manuscript received 8 April 2002, revised II February 2003, accepted 4 March 2003 p-Sulfonamidophenylazobisacetoxime has been used for spectrophotometric determination of iron(III) at 405 nm, keeping the pH at 2.5-3.0. Beer's law is obeyed in the range (4 to 24) x 10-5 M. The molar absorptivity and Sandell's sensitivity values are 1853 dm3 mol-1 cm-1 and 30.14 ng cm-2, respectively.

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Department of Chemistry, M. L. Sukhadia University, Udaipur-313 00 I, India E-mail : akumargoswami@rediffmail.com Manuscript received 8 April 2002, revised II February 2003, accepted 4 March 2003 p-Sulfonamidophenylazobisacetoxime has been used for spectrophotometric determination of iron(III) at 405 nm, keeping the pH at 2.5-3.0. Beer's law is obeyed in the range (4 to 24) x 10-5 M. The molar absorptivity and Sandell's sensitivity values are 1853 dm3 mol-1 cm-1 and 30.14 ng cm-2, respectively.

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Available abstract

Department of Chemistry, M. L. Sukhadia University, Udaipur-313 00 I, India E-mail : akumargoswami@rediffmail.com Manuscript received 8 April 2002, revised II February 2003, accepted 4 March 2003 p-Sulfonamidophenylazobisacetoxime has been used for spectrophotometric determination of iron(III) at 405 nm, keeping the pH at 2.5-3.0. Beer's law is obeyed in the range (4 to 24) x 10-5 M. The molar absorptivity and Sandell's sensitivity values are 1853 dm3 mol-1 cm-1 and 30.14 ng cm-2, respectively.

Key concepts: Chemistry, Analytical Chemistry (journal), Chromatography

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