Analytical application of p-sulfonamidophenylazo-bis-acetoxime in the spectrophotometric determination of iron(III)
Saba Khan, Rekha Dashora, Anita Mehta, A.K. Goswami
Abstract
Saba Khan, Rekha Dashora, Anita Mehta, A.K. Goswami
Abstract
Department of Chemistry, M. L. Sukhadia University, Udaipur-313 00 I, India E-mail : akumargoswami@rediffmail.com Manuscript received 8 April 2002, revised II February 2003, accepted 4 March 2003 p-Sulfonamidophenylazobisacetoxime has been used for spectrophotometric determination of iron(III) at 405 nm, keeping the pH at 2.5-3.0. Beer's law is obeyed in the range (4 to 24) x 10-5 M. The molar absorptivity and Sandell's sensitivity values are 1853 dm3 mol-1 cm-1 and 30.14 ng cm-2, respectively.
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Department of Chemistry, M. L. Sukhadia University, Udaipur-313 00 I, India E-mail : akumargoswami@rediffmail.com Manuscript received 8 April 2002, revised II February 2003, accepted 4 March 2003 p-Sulfonamidophenylazobisacetoxime has been used for spectrophotometric determination of iron(III) at 405 nm, keeping the pH at 2.5-3.0. Beer's law is obeyed in the range (4 to 24) x 10-5 M. The molar absorptivity and Sandell's sensitivity values are 1853 dm3 mol-1 cm-1 and 30.14 ng cm-2, respectively.
Key concepts: Chemistry, Analytical Chemistry (journal), Chromatography