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Optimised chlorine-free bleaching systems for jute and jute/cotton blend fabrics

Jackie Y. Cai, S.K. David

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Abstract

A sequential two-stage bleaching process using peracetic acid followed by hydrogen peroxide. has been developed specifically for jute and jute/cotton blend fabrics. A peracetic acid system is optimised for jute by the selection of suitable buffering and stabilising agents. A superior bleaching effect is obtained by using TSPP as a stabiliser in the presence of a phosphate buffer, under mildly alkaline conditions (PH 8.0-8.5), whereby excellent fibre brightness may be achieved at temperatures as low as 40-60°C. A conventional H202-N~Si03 system has also been further optimised for jute by the exclusive use of sodium metasilicate at high concentrations of 3.5-4.0 g/l. Sequential bleaching with these independently optimised system results in an excellent degree of overall fabric brightness, such that the 1st-stage peracetic acid bleach may be carried out at relatively low temperature (30-40°C). This combination process therefore offers an effective, environmentally favourable and energy efficient option to conventional peroxide-utilising and chlorine bleaching processes. A further advantage is that it may also be successfully extended to the bleaching of jute/cotton blends. Furthermore, fabric tensile strength loss is less than that observed with high temperature H202-N~Si03 bleaching and the tendency towards photoyellowing of the combination bleached fabrics is not adversely affected, despite the high level of fabric brightness achieved.

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What this paper is about

A sequential two-stage bleaching process using peracetic acid followed by hydrogen peroxide. has been developed specifically for jute and jute/cotton blend fabrics. A peracetic acid system is optimised for jute by the selection of suitable buffering and stabilising agents. A superior bleaching effect is obtained by using TSPP as a stabiliser in the presence of a phosphate buffer, under mildly alkaline conditions (PH 8.0-8.5), whereby excellent fibre brightness may be achieved at temperatures as low as 40-60°C. A conventional H202-N~Si03 system has also been further optimised for jute by the exclusive use of sodium metasilicate at high concentrations of 3.5-4.0 g/l. Sequential bleaching with these independently optimised system results in an excellent degree of overall fabric brightness, such that the 1st-stage peracetic acid bleach may be carried out at relatively low temperature (30-40°C). This combination process therefore offers an effective, environmentally favourable and energy efficient option to conventional peroxide-utilising and chlorine bleaching processes. A further advantage is that it may also be successfully extended to the bleaching of jute/cotton blends. Furthermore, fabric tensile strength loss is less than that observed with high temperature H202-N~Si03 bleaching and the tendency towards photoyellowing of the combination bleached fabrics is not adversely affected, despite the high level of fabric brightness achieved.

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Available abstract

A sequential two-stage bleaching process using peracetic acid followed by hydrogen peroxide. has been developed specifically for jute and jute/cotton blend fabrics. A peracetic acid system is optimised for jute by the selection of suitable buffering and stabilising agents. A superior bleaching effect is obtained by using TSPP as a stabiliser in the presence of a phosphate buffer, under mildly alkaline conditions (PH 8.0-8.5), whereby excellent fibre brightness may be achieved at temperatures as low as 40-60°C. A conventional H202-N~Si03 system has also been further optimised for jute by the exclusive use of sodium metasilicate at high concentrations of 3.5-4.0 g/l. Sequential bleaching with these independently optimised system results in an excellent degree of overall fabric brightness, such that the 1st-stage peracetic acid bleach may be carried out at relatively low temperature (30-40°C). This combination process therefore offers an effective, environmentally favourable and energy efficient option to conventional peroxide-utilising and chlorine bleaching processes. A further advantage is that it may also be successfully extended to the bleaching of jute/cotton blends. Furthermore, fabric tensile strength loss is less than that observed with high temperature H202-N~Si03 bleaching and the tendency towards photoyellowing of the combination bleached fabrics is not adversely affected, despite the high level of fabric brightness achieved.

Key concepts: Peracetic acid, Bleach, Hydrogen peroxide, Chlorine, Pulp and paper industry, Stabiliser, Chemistry, Ultimate tensile strength

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