ScholarLens Back to search
1985•OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)Requires access

Mechanism for the oxidation of carbon monoxide on supported catalysts. I. Low temperature oxidation of carbon monoxide of Pd/. gamma. -Al/sub 2/O/sub 3/

G.N. Kakniashvili, David Dulin, E. G. ISAEVA, Yu.A. Mishchenko

Open publisher page 0 citations

Abstract

A study was carried out on the mechanism of the catalytic oxidation of CO on Pd/..gamma..-Al/sub 2/O/sub 3/ at less than or equal to 150/sup 0/C using labelled oxygen and thermal desorption analysis. The reaction was found to proceed by the reaction of the intermediate complexes of CO molecules with the Al/sub 2/O/sub 3/ hydroxyl groups. A combined mechanism was proposed for the formation and decomposition of carboxyl species, in which adsorbed oxygen reoxidizes the reduced palladium atoms and provides for decomposition of the carboxyl species with the formation of CO/sub 2/ and regeneration of the OH groups.

About this research paper

What this paper is about

A study was carried out on the mechanism of the catalytic oxidation of CO on Pd/..gamma..-Al/sub 2/O/sub 3/ at less than or equal to 150/sup 0/C using labelled oxygen and thermal desorption analysis. The reaction was found to proceed by the reaction of the intermediate complexes of CO molecules with the Al/sub 2/O/sub 3/ hydroxyl groups. A combined mechanism was proposed for the formation and decomposition of carboxyl species, in which adsorbed oxygen reoxidizes the reduced palladium atoms and provides for decomposition of the carboxyl species with the formation of CO/sub 2/ and regeneration of the OH groups.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

A study was carried out on the mechanism of the catalytic oxidation of CO on Pd/..gamma..-Al/sub 2/O/sub 3/ at less than or equal to 150/sup 0/C using labelled oxygen and thermal desorption analysis. The reaction was found to proceed by the reaction of the intermediate complexes of CO molecules with the Al/sub 2/O/sub 3/ hydroxyl groups. A combined mechanism was proposed for the formation and decomposition of carboxyl species, in which adsorbed oxygen reoxidizes the reduced palladium atoms and provides for decomposition of the carboxyl species with the formation of CO/sub 2/ and regeneration of the OH groups.

Key concepts: Carbon monoxide, Chemistry, Catalysis, Decomposition, Oxygen, Inorganic chemistry, Reaction mechanism, Desorption

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Mechanism for the oxidation of carbon monoxide on supported catalysts. I. Low temperature oxidation of carbon monoxide of Pd/. gamma. -Al/sub 2/O/sub 3/ — Research Paper | ScholarLens