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1990•Bulletin of the Chemical Society of JapanOpen access

Reaction of a Thioaminyl Diradical with 7,7,8,8-Tetracyanoquinodimethane (TCNQ). The Formation of a Cyclophane Compound

Yozo Miura, Tsuguyori Ohana, Teruo Kunishi

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Abstract

Abstract The reactions of thioaminyl mono- (MONOR) and diradicals (DIR) with 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been investigated. The reactions of TCNQ with MONOR gave 1:2 adducts of TCNQ and MONOR in 85–88% yields, while the reaction with DIR afforded either a cyclophane compound (77%), or an alternating polymer of TCNQ and DIR (59 wt%), dependent on the structures of DIR.

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Abstract The reactions of thioaminyl mono- (MONOR) and diradicals (DIR) with 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been investigated. The reactions of TCNQ with MONOR gave 1:2 adducts of TCNQ and MONOR in 85–88% yields, while the reaction with DIR afforded either a cyclophane compound (77%), or an alternating polymer of TCNQ and DIR (59 wt%), dependent on the structures of DIR.

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Available abstract

Abstract The reactions of thioaminyl mono- (MONOR) and diradicals (DIR) with 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been investigated. The reactions of TCNQ with MONOR gave 1:2 adducts of TCNQ and MONOR in 85–88% yields, while the reaction with DIR afforded either a cyclophane compound (77%), or an alternating polymer of TCNQ and DIR (59 wt%), dependent on the structures of DIR.

Key concepts: Tetracyanoquinodimethane, Chemistry, Diradical, Cyclophane, Cryptand, Photochemistry, Polymer chemistry, Stereochemistry

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Reaction of a Thioaminyl Diradical with 7,7,8,8-Tetracyanoquinodimethane (TCNQ). The Formation of a Cyclophane Compound — Research Paper | ScholarLens