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2001•Chemistry LettersRequires access

Electrochemical Influence of Tridentate Polypyrazolylborate Ligands: Syntheses and Electrochemistry of Bis(η3-polypyrazolylborato)ruthenium(II) Complexes

Masayoshi Onishi, Siho Kumagae, Keiko Asai, Hiroyuki Kawano, Yasuhiro Shigemitsu

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Abstract

Abstract Concerning electrochemically reversible [Ru(III)]/[Ru(II)] redox couples of the substituted bis(η3-polypyrazolylborato)ruthenium(II) complexes [Ru(L1)(L2)], two polypyrazolylborate ligands, L1 and L2, were independently exerted on the oxidation half-wave potentials (E1/2) of the couples. Relative contributions δE(L) of the respective polypyrazolylborates to the E1/2 values were evaluated.

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Abstract Concerning electrochemically reversible [Ru(III)]/[Ru(II)] redox couples of the substituted bis(η3-polypyrazolylborato)ruthenium(II) complexes [Ru(L1)(L2)], two polypyrazolylborate ligands, L1 and L2, were independently exerted on the oxidation half-wave potentials (E1/2) of the couples. Relative contributions δE(L) of the respective polypyrazolylborates to the E1/2 values were evaluated.

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Available abstract

Abstract Concerning electrochemically reversible [Ru(III)]/[Ru(II)] redox couples of the substituted bis(η3-polypyrazolylborato)ruthenium(II) complexes [Ru(L1)(L2)], two polypyrazolylborate ligands, L1 and L2, were independently exerted on the oxidation half-wave potentials (E1/2) of the couples. Relative contributions δE(L) of the respective polypyrazolylborates to the E1/2 values were evaluated.

Key concepts: Chemistry, Ruthenium, Electrochemistry, Combinatorial chemistry, Medicinal chemistry, Stereochemistry, Organic chemistry, Electrode

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Electrochemical Influence of Tridentate Polypyrazolylborate Ligands: Syntheses and Electrochemistry of Bis(η3-polypyrazolylborato)ruthenium(II) Complexes — Research Paper | ScholarLens